The 20 Greatest TV Couples of All Time | Chuck and Blair, <em>Gossip Girl</em> | EW.com 

Nick Jonas, Janelle Monae, James Corden and more at EW\'s ultimate pop culture festival.

could ever compare to Chuck and Blair, mainly because they were the perfect example of two people who really were better together. In the beginning, Chuck was nothing but a womanizer while Blair would do pretty much anything to defend her title as Queen B. We can all agree that, individually, they were two people no one wanted as enemies, but they ended up bringing out the best in each other.

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